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Glossary

Unsaponifiable Matter

Also written as: unsaponifiables, unsaps, non-saponifiable fraction

Summary

Unsaponifiable matter is the fraction of a fat that does not form soap when boiled with alkali, mainly triterpene alcohols, sterols, tocopherols and hydrocarbons. Shea butter is unusually rich in it, which is why the fraction is prized in cosmetics.

The fraction is attributed to the skin-conditioning and anti-inflammatory reputation of shea, through triterpene esters such as lupeol and amyrin derivatives. Unrefined butter keeps more of it than refined; a low value in an unrefined sample suggests over-processing or blending. The usual method is AOCS Ca 6a-40.

Part of the shea butter glossary · Complete guide to shea butter

Last reviewed September 2026 by EMI Agro Industries QC team.